PSG had the chance to go ahead just minutes into their quarter-final when Neymar, 28, found himself one-on-one with Atalanta’s goalkeeper.
The Brazilian – who is the most expensive footballer in history at nearly £200million, Neymar set himself up perfectly but failed to pull the trigger and put his side 1-0 up.
Neymar’s shot somehow missed the target, going well wide to the right of the post.